214678-41-8

Basic information

• Product Name: (1R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-(2-hydroxy-ethyl)-cyclohex-2-enol
• Synonyms: (1R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-(2-hydroxy-ethyl)-cyclohex-2-enol
• CAS NO: 214678-41-8
• Molecular Weight: 272.46
• Mol File: 214678-41-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-(2-hydroxy-ethyl)-cyclohex-2-enol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-(2-hydroxy-ethyl)-cyclohex-2-enol(214678-41-8)
• EPA Substance Registry System: (1R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-(2-hydroxy-ethyl)-cyclohex-2-enol(214678-41-8)

Safety Data

• Hazardous Substances Data: 214678-41-8(Hazardous Substances Data)

Upstream product

• 214678-40-7 (1R,4S,4aR,5R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-5-(2-hydroxy-ethyl)-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 214678-39-4 [(1R,4S,4aR,5R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl]-acetic acid ethyl ester 
• 214678-36-1 ((1R,4S,4aR,5S,8aS)-5-Hydroxy-8-oxo-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-yl)-acetic acid ethyl ester 
• 214678-37-2 ((1R,4S,4aR,5R,8aS)-5-Hydroxy-8-oxo-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl)-acetic acid ethyl ester 
• 214678-29-2 ((1R,4S,4aR,5S,8R,8aS)-5,8-Dihydroxy-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-yl)-acetic acid ethyl ester 
• 214678-38-3 ((1R,4S,4aR,5R,8R,8aS)-5,8-Dihydroxy-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl)-acetic acid ethyl ester 
• 214678-27-0 ((1R,4S,4aR,5S,8R,8aS)-8-Acetoxy-5-hydroxy-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-yl)-acetic acid ethyl ester 

Downstream Products

• 214678-47-4 Acetic acid (1R,4R)-1-(2-acetoxy-ethyl)-4-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enyl ester 
• 214678-42-9 4-(tert-Butyl-dimethyl-silanyloxy)-1-(2-hydroxy-ethyl)-cyclohexanol 
• 107389-91-3 4-hydroxy-4-(2-hydroxyethyl)cyclohexanone 
• 93675-85-5 rengyol 
• 101489-38-7 trans-1-(2-hydroxyethyl)cyclohexane-1,4-diol 
• 93675-95-7 rengyoxide diacetate 
• 176598-06-4 1-Oxa-spiro[3.5]nonan-7-ol 
• 165197-71-7 cleorindicin E 
• 183626-28-0 (-)-cleroindicin C 
• 214678-51-0 4-Nitro-benzoic acid (3aR,6S,7aS)-3a-hydroxy-octahydro-benzofuran-6-yl ester 
• 214678-45-2 Toluene-4-sulfonic acid 2-[4-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-cyclohexyl]-ethyl ester 
• 165197-71-7 isocleorindicin E 
• 214678-48-5 Acetic acid (1R,4R)-1-(2-acetoxy-ethyl)-4-hydroxy-cyclohex-2-enyl ester 

Relevant articles and documents

A stereocontrolled route to cyclohexylethanoid natural products

Rengyol and seven related cyclohexylethanoid natural products have been synthesized in a stereocontrolled manner from a common starting material. In the present study the absolute configuration of the three chiral products has been determined and the first synthesis of a cyclohexylethanoid natural product bearing an oxetane ring has been accomplished.