214752-00-8

Basic information

• Product Name: (E,2R,5S)-7-methyl-5-(2,4,6-trimethylbenzenesulfonyl)amino-2-phenyloct-3-ene
• Synonyms: (E,2R,5S)-7-methyl-5-(2,4,6-trimethylbenzenesulfonyl)amino-2-phenyloct-3-ene
• CAS NO: 214752-00-8
• Molecular Weight: 399.598
• Mol File: 214752-00-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E,2R,5S)-7-methyl-5-(2,4,6-trimethylbenzenesulfonyl)amino-2-phenyloct-3-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (E,2R,5S)-7-methyl-5-(2,4,6-trimethylbenzenesulfonyl)amino-2-phenyloct-3-ene(214752-00-8)
• EPA Substance Registry System: (E,2R,5S)-7-methyl-5-(2,4,6-trimethylbenzenesulfonyl)amino-2-phenyloct-3-ene(214752-00-8)

Safety Data

• Hazardous Substances Data: 214752-00-8(Hazardous Substances Data)

Downstream Products

• 93-53-8 (S)-2-phenyl-propionaldehyde 
• 186801-24-1 N-((S)-1-Formyl-3-methyl-butyl)-2,4,6-trimethyl-benzenesulfonamide 
• 37778-99-7 (S)-2-phenyl-1-propanol 
• 214752-01-9 (2S)-N-(2,4,6-trimethylbenzenesulfonyl)-2-amino-4-methyl-pentanol 

Relevant articles and documents

Reactions of n-arylsulfonyl-2,3-cis- and n-arylsulfonyl-2,3-frans-3-alkyl-2-vinylaziridines with organocopper reagents: importance of 2,3-cis-stereochemistry in controlling regio- and stereoselectivity

Although reactions of 2,3-trans-N-arylsulfonyl-3-alkyl-2-alkenylaziridines with organocopper reagents give a mixture of two or three products, the corresponding 2,3-cis-isomers provide a highly efficient route to synthetically important nonracemic CE)-allylamines. It is also found that the reaction proceeds via the well-known anti-SN2′ pathway.