214827-40-4

Basic information

• Product Name: (2E,4E)-Octa-2,4-dienoic acid (4S,5S,7R,7aS)-5-(2-benzenesulfonyl-1,1-dimethyl-ethyl)-5-methoxy-2-oxo-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-4,5,7,7a-tetrahydro-2H-furo[2,3-c]pyran-4-yl ester
• Synonyms: (2E,4E)-Octa-2,4-dienoic acid (4S,5S,7R,7aS)-5-(2-benzenesulfonyl-1,1-dimethyl-ethyl)-5-methoxy-2-oxo-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-4,5,7,7a-tetrahydro-2H-furo[2,3-c]pyran-4-yl ester
• CAS NO: 214827-40-4
• Molecular Weight: 632.772
• Mol File: 214827-40-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2E,4E)-Octa-2,4-dienoic acid (4S,5S,7R,7aS)-5-(2-benzenesulfonyl-1,1-dimethyl-ethyl)-5-methoxy-2-oxo-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-4,5,7,7a-tetrahydro-2H-furo[2,3-c]pyran-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,4E)-Octa-2,4-dienoic acid (4S,5S,7R,7aS)-5-(2-benzenesulfonyl-1,1-dimethyl-ethyl)-5-methoxy-2-oxo-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-4,5,7,7a-tetrahydro-2H-furo[2,3-c]pyran-4-yl ester(214827-40-4)
• EPA Substance Registry System: (2E,4E)-Octa-2,4-dienoic acid (4S,5S,7R,7aS)-5-(2-benzenesulfonyl-1,1-dimethyl-ethyl)-5-methoxy-2-oxo-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-4,5,7,7a-tetrahydro-2H-furo[2,3-c]pyran-4-yl ester(214827-40-4)

Safety Data

• Hazardous Substances Data: 214827-40-4(Hazardous Substances Data)

Upstream product

• 22329-75-5 (2E,4E)-octadienoic acid 
• 214827-34-6 (4S,5S,7R,7aS)-5-(2-Benzenesulfonyl-1,1-dimethyl-ethyl)-4-hydroxy-5-methoxy-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-4,5,7,7a-tetrahydro-furo[2,3-c]pyran-2-one 
• 214827-32-4 (2S,3S,5S,6R)-2-(2-Benzenesulfonyl-1,1-dimethyl-ethyl)-3,5-bis-(tert-butyl-dimethyl-silanyloxy)-4-[2-(tert-butyl-diphenyl-silanyloxy)-eth-(E)-ylidene]-2-methoxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran 
• 214827-31-3 (3S,5S,6R)-2-(2-Benzenesulfonyl-1,1-dimethyl-ethyl)-3,5-bis-(tert-butyl-dimethyl-silanyloxy)-4-[2-(tert-butyl-diphenyl-silanyloxy)-eth-(E)-ylidene]-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-2-ol 
• 214827-33-5 (2S,3S,5S,6R)-2-(2-Benzenesulfonyl-1,1-dimethyl-ethyl)-4-[2-hydroxy-eth-(E)-ylidene]-2-methoxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-3,5-diol 

Relevant articles and documents

Synthesis of the C17-C27 fragment of bryostatin 3

The key synthetic intermediate corresponding to the C17 - C27 positions of bryostatin 3, has successfully been synthesized. The newly constructed stereogenic centers were unambiguously confirmed by X-ray crystallographic analysis.