214849-95-3Relevant academic research and scientific papers
Synthesis of differentially protected myo- and chiro-inositols from D-xylose: Stereoselectivity in intramolecular SmI2-promoted pinacol reactions
Luchetti, Giovanni,Ding, Kejia,Kornienko, Alexander,D'Alarcao, Marc
experimental part, p. 3148 - 3154 (2009/04/07)
Methods for the enantioselective conversion of D-xylose into differentially protected myo-inositol and L-chiro-inositol have been developed. The key transformation is a highly diastereoselective intramolecular SmI 2-promoted pinacol coupling. T
Practical synthesis of a differentially protected myo-inositol
Kornienko, Alexander,Turner, David I.,Jaworek, Christine H.,D'Alarcao, Marc
, p. 2783 - 2786 (2007/10/03)
An enantiospecific synthesis of 3,4,5-tri-O-benzyl-6-O- triisopropylsilyl-D-myo-inositol from D-xylose is reported. The synthesis features a diastereofacially selective SmI2-promoted pinacol cyclization.
