214902-52-0Relevant academic research and scientific papers
Stereochemistry in palladium- and nickel-catalyzed addition of phenylmagnesium bromide to unsaturated carbohydrates
Moineau, Christophe,Bolitt, Veronique,Sinou, Denis
, p. 157 - 162 (1998)
Palladium complex PdCl2(dppf) and nickel complex NiCl2(dppe) catalyze cross-coupling of unsaturated aryloxy carbohydrates with phenylmagnesium bromide. The nickel catalyst leads to inversion of configuration at the anomeric center wh
