215-11-2Relevant articles and documents
Synthesis of extended triphenylenes by palladium-catalyzed [2+2+2] cycloaddition of triphenylynes
Romero, Carmen,Pena, Diego,Perez, Dolores,Guitian, Enrique
, p. 5677 - 5684 (2008/03/13)
The synthesis of orttho-(trimethylsilyl)triphenylenyl triflates 7 is described. Fluoride-induced decomposition of these triflates leads to the generation of didehydrotriphenylenes (triphenylynes). 6. These arynes undergo [4+2] cycloadditions with dienes to afford the corresponding Diels-Alder adducts or palladium-catalyzed formal [2+2+2] cycloadditions to afford extended triphenylenes.