215102-91-3Relevant academic research and scientific papers
Four and eight membered metal containing boron-nitrogen-heterocycles. Formation and structures in dependence on the steric requirement of their substituents
Albrecht,Elter,Noltemeyer,Meller
, p. 1514 - 1518 (2008/10/09)
TripB(NRLi)2 (Trip = 2,4,6-triisopropylphenyl, R = Me (IIa), CH2Me (IIb), CHMe2 (IIc), CMe3 (IId) reacts with dibromo(dimethyl)tin to give eight membered (IIIa, IIIb) and four membered metallacycles (IVc and IVd). If tetrahalides (GeCl4, SnCl4) are the reaction partners, the spiro compounds Vc and VId are obtained from IIc and IId resp. The compounds are characterized by their m.s. and n.m.r. (1H, 11B, 13C, 19F, 119Sn) spectra and by elemental analyses. An X-ray structure analysis was performed for IIIa.
