21551-67-7

Basic information

• Product Name: 2,5-Cyclohexadiene-1,4-dione, 2,2'-(1,16-hexadecanediyl)bis[3-hydroxy-6-methoxy-
• CAS NO: 21551-67-7
• Molecular Formula: C30H42O8
• Molecular Weight: 530.659
• Mol File: 21551-67-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadiene-1,4-dione, 2,2'-(1,16-hexadecanediyl)bis[3-hydroxy-6-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadiene-1,4-dione, 2,2'-(1,16-hexadecanediyl)bis[3-hydroxy-6-methoxy-(21551-67-7)
• EPA Substance Registry System: 2,5-Cyclohexadiene-1,4-dione, 2,2'-(1,16-hexadecanediyl)bis[3-hydroxy-6-methoxy-(21551-67-7)

Safety Data

• Hazardous Substances Data: 21551-67-7(Hazardous Substances Data)

Upstream product

• 87746-52-9 1,4-dimethoxy-2,5-di(methoxymethyloxy)benzene 
• 99608-42-1 7-bromo-1-(2,5-dimethoxy-3,6-dimethoxymethyloxyphenyl)heptane 
• 162337-88-4 3-(7-Iodo-heptyl)-1,4-dimethoxy-2,5-bis-methoxymethoxy-benzene 
• 99608-52-3 9-(2,5-dimethoxy-3,6-dimethoxymethyloxyphenyl)nonana-1-yne 
• 99621-90-6 C₃₂H₄₄O₈ 
• 61621-77-0 1,16-Bis-(3,5-dimethoxy-phenyl)-hexadec-8-yne-3,14-dione 
• 61621-79-2 C₃₂H₄₆O₄ 
• 61621-82-7 C₃₂H₅₀O₄ 
• 61621-73-6 1,14-bis-diazo-tetradec-7-yne-2,13-dione 
• 61621-74-7 1,14-dibromo-tetradec-7-yne-2,13-dione 
• 61621-71-4 dodec-6-ynedioic acid 
• 116138-87-5 C₃₀H₃₈O₈ 
• 116138-67-1 C₃₀H₃₈O₈ 
• 162337-89-5 C₄₀H₆₄O₁₂ 

Downstream Products

• 871-70-5 octadecanedioic acid 
• 21551-68-8 1,16-Bis-<2-acetoxy-5-methoxy-1,4-benzochinonyl-(3)>-hexadecan 
• 21772-26-9 1,16-Bis-(2,5-bis-(methylamino)-p-benzochinonyl-⁽³⁾)-hexadecan 
• 21772-27-0 Dihydroardisiachinon A-dimethylaether 

Relevant articles and documents

Naturally occurring 5-lipoxygenase inhibitors. VI. Structures of ardisiaquinones D, E, and F from Ardisia sieboldii

New 1,4-benzoquinone derivatives, ardisiaquinones D (2), E (4), and F (5) along with the known ardisiaquinones A (1) and B (3) have been isolated from the leaves of Ardisia sieboldii (Myrsinaceae) and shown to be 5-lipoxygenase inhibitors. Their structure

Synthesis of New 3-(-2-Alkenyl)-2-hydroxy-5-methoxy-p-benzoquinones via Claisen Rearrangement of Original 5-Methoxy-4-(2-propenyloxy)-o-benzoquinones

The Claisen rearrangement is extended to compounds containing the benzoquinone moiety, obtained by regioselective nucleophilic substitution on 4-(p-methoxyphenoxy)-5-methoxy-o-benzoquinone (1).In the most general case, 5-methoxy-4-(2-propenyloxy)-o-benzoquinones 3 rearrange quantitatively into (E)-3-(2-alkenyl-2-hydroxy-5-methoxy-p-benzoquinones 4.Furfuryl or (2-thienyl)methyl ethers isomerize to 3-(2-methyl-3-furyl)- and 3-(2-methyl-3-thienyl)-2-hydroxy-5-methoxy-p-benzoquinones.This new synthetic method provides an efficient route to new hydroxybenzoquinones closelyrelated to natural compounds.Thus, dihydroardisiaquinone A is synthesized in 5 steps from p-methoxyphenol.