215729-87-6

Basic information

• Product Name: (C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))]BF₄
• CAS NO: 215729-87-6
• Molecular Weight: 429.97
• Mol File: 215729-87-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))]BF₄(215729-87-6)
• EPA Substance Registry System: (C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(PH(C₆H₅)(C(CH₃)3))]BF₄(215729-87-6)

Safety Data

• Hazardous Substances Data: 215729-87-6(Hazardous Substances Data)

Upstream product

• 6002-31-9 t-butylphenylphosphine 

Downstream Products

• 215729-92-3 1-carbonyl-1-(η(5)-cyclopentadienyl)-1-ferra-2-(tert-butyl)-2-phenyl-2-phospha-3-thione-4-methyl-4-aza-cyclopentan-5-one 

Relevant articles and documents

Fuenfgliedrige Phosphametallacyclen Cp(OC)M-PR2-C(=S)-N(ME)-C(=O): Darstellung durch [3+2]-Cycloaddition der Metallo-phosphane Cp(OC)2M-PR2 (M=Fe, Ru; R=Alkyl, Aryl) mit Methylisothiocyanat: Uebergangsmetall-substituierte

Deprotonation of the cationic phosphane complexes {Cp(OC)2[R2(H)P]M}X (M=Fe, Ru; X=BF4, PF6) (1a-d) with KOt-Bu in the presence of methylisothiocyanate (2) yields the five-membered phospha-metallacycles Cp(OC)M-