215917-64-9

Upstream product

• 5633-85-2 2,7-dimethyl-octane-4,5-dione 
• 22538-57-4 pyridine-2,6-bis(carboximidehydrazide) 

Downstream Products

• 940311-82-0 RuCl₂(PPh₃)(2,6-bis(5,6-bis(iso-butyl)-1,2,4-triazin-3-yl)pyridine) 

Relevant academic research and scientific papers

Two pseudo-N3 ligands and the catalytic activity of their ruthenium(II) complexes in transfer hydrogenation and hydrogenation of ketones

Complex RuCl2(PPh3)(iBu-BTP) (5) was synthesized by the reaction of 2,6-bis(5,6-bis(iso-butyl)-1,2,4-triazin-3-yl)pyridine (iBu-BTP) and RuCl2(PPh3)3 in refluxing toluene, and its molecular structure was confirmed by X-ray crystallographic determination. Complex 5 was applied as a catalyst for transfer hydrogenation of ketones and exhibited catalytic activity comparable to RuCl2(PPh3)(Me4BPPy) (1) (Me4BPPy = bis(3,5-dimethylpyrazol-1-yl)pyridine) in some cases. The difference between the catalytic activity of 5 and 1 is attributed to the significantly different arrangement and positions of the PPh3 and chlorides and also to the different electron density on the N-heterocycles. Complex 1 exhibited good to excellent catalytic activity in hydrogenation of ketones under mild conditions. These results have suggested new applications of iBu-BTP and Me4BPPy as promising planar tridentate pseudo-N3 ligands to construct highly active transition-metal catalysts.