216020-49-4Relevant academic research and scientific papers
Synthesis and characterisation of a pair of azo anion radicals bonded to ruthenium(II)
Shivakumar, Maya,Pramanik, Kausikisankar,Ghosh, Prasanta,Chakravorty, Animesh
, p. 2103 - 2104 (1998)
The reactions of 1-methyl-2-(p-chlorophenylazo)imidazole (L1) and 2-(phenylazo)pyridine (L2) with [Ru(H)(X)(CO)(PPh3)3] (X = Cl, Br) have afforded the green paramagnetic (S = 1/2) and EPR-active (g ≈ 2.00) title anion radical complexes [Ru(L1-)(Cl)(CO)(PPh3)2] 1 and [Ru(L2-)(Br)(CO)(PPh3)2] 2 in which the N-N bond lengths lie near 1.35 A.
