216305-05-4

Basic information

• Product Name: 1-(9-fluorenyl)-1-<1-(1,3-cyclopentadienyl)>-1-phenylethane
• CAS NO: 216305-05-4
• Molecular Weight: 334.461
• Mol File: 216305-05-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(9-fluorenyl)-1-<1-(1,3-cyclopentadienyl)>-1-phenylethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(9-fluorenyl)-1-<1-(1,3-cyclopentadienyl)>-1-phenylethane(216305-05-4)
• EPA Substance Registry System: 1-(9-fluorenyl)-1-<1-(1,3-cyclopentadienyl)>-1-phenylethane(216305-05-4)

Safety Data

• Hazardous Substances Data: 216305-05-4(Hazardous Substances Data)

Upstream product

• 86-73-7 9H-fluorene 
• 2320-32-3 6-methyl-6-phenylfulvene 

Downstream Products

• 216853-00-8 1-η(3)-(9-fluorenylidene)-1-η(5)-(1-cyclopentadienylidene)-1-phenylethane zirconium dichloride 

Relevant articles and documents

C1-Bridged fluorenylidene cyclopentadienylidene complexes of the type (C13H8-CR1R2-C5H 3R)ZrCl2 (R1, R2=alkyl, phenyl, alkenyl; R=H, alkyl, alkenyl, substituted silyl) as catalyst precursors for the polymerization of ethylene and propylene

The synthesis and characterization of 14 new C1-bridged fluorenylidene cyclopentadienylidene complexes of zirconium is described. After activation with methylaluminoxane (MAO), these metallocene complexes can be used for the polymerization of ethylene and propylene. Various substituents in the bridge and in position 3 of the cyclopentadienylidene ligand have a strong influence on the activity of the corresponding catalysts and the molecular weights of the formed polyolefins. The bulkiness of the substituents in position 3 of the cyclopentadienylidene ring determines the extent of the stereospecific polymerization of propylene. Substituents can be selected that produce hemitactic, syndiotactic or isotactic polypropylenes and/or the corresponding block copolymers.