216320-16-0Relevant articles and documents
Additions of Organocopper Reagents and Heteroatom Nucleophiles to l-Phenylseleno-2-(p-toluenesulfonyl)ethyne. Preparation of Vinyl and Allenic Sulfones and Formation of Michael, Anti-Michael, and Rearrangement Products
Back, Thomas G.,Bethell, Richard J.,Parvez, Masood,Wehrli, Daniel
, p. 7908 - 7919 (2007/10/03)
l-Phenylseleno-2-(p-toluenesulfonyl)ethyne (4) was produced nearly quantitatively from p-(toluenesulfonyl)ethyne and benzeneselenenyl chloride. It undenvent stereo- and regioselective synadditions of organocopper reagents RCu(CN)Li to the β-position of th