216386-91-3Relevant academic research and scientific papers
Carbocyclization reaction of malonate derivatives with allylsilane moiety mediated by AICI3-n-BU3N
Imazeki, Shigeaki,Kinoshita, Ryohiko,Akiyama, Takahiko
experimental part, p. 972 - 978 (2009/06/05)
Allylsilane bearing malonate moiety underwent intramolecular carbocyclization reaction by means of AlCl3-n-BU3N to give silyl-substituted cyclopentanes in good yields.
Stereoselective synthesis of 2,3,5-substituted tetrahydrofurans by silicon-directed cyclization of allylsilanes bearing a hydroxy moiety
Akiyama, Takahiko,Ishida, Yuhsuke
, p. 1150 - 1152 (2007/10/03)
Acid promoted cyclization of bishomoallylic alcohols bearing allylsilanes proceeded smoothly by way of β-silyl carbocation intermediate to furnish tetrahydrofurans highly stereoselectively.
