216446-38-7Relevant academic research and scientific papers
Flash vacuum pyrolysis of some N-benzylbenzotriazoles and N-benzylbenzisoxazolones
Khalafy, Jabbar,Prager, Rolf H.
, p. 925 - 929 (2007/10/03)
The flash vacuum pyrolysis products of 2-(benzotriazol-l-ylmethyl) benzonitrile, methyl 2-(benzotriazol-lylmethyl)benzoate and the corresponding benzisoxazolones have been characterized. The benzotriazoles lose nitrogen to give diradicals which undergo intramolecular hydrogen-atom transfer or cyclization, while the benzisoxazolones rearrange initially to the corresponding benzaldehyde N-(2-carboxyphenyl)imines which undergo subsequent intramolecular addition reactions.
