216577-82-1Relevant academic research and scientific papers
Control of the ambident reactivity of the nitrite ion
Dong, Hai,Rahm, Martin,Thota, Niranjan,Deng, Lingquan,Brinck, Tore,Ramstroem, Olof
, p. 648 - 653 (2013/02/26)
In previous studies, it was reported that a neighbouring equatorial ester group is essential for a good yield of nitrite-mediated triflate inversion, whereas with neighbouring benzyl ether groups or axial ester groups, mixtures are generally produced. In
Stereospecific ester activation in nitrite-mediated carbohydrate epimerization
Dong, Hai,Pei, Zhichao,Ramstroem, Olof
, p. 3306 - 3309 (2007/10/03)
The Lattrell-Dax method of nitrite-mediated substitution of carbohydrate triflates is an efficient method to generate structures of inverse configuration. In the present study, epimerization of gluco- and galactopyranoside derivatives to the corresponding
Preparation of L-lyxo-hexos-5-ulose through C-3 epimerization of bis-glycopyranosides of L-arabino-hexos-5-ulose 1
Barili, Pier Luigi,Berti, Giancarlo,Catelani, Giorgio,D'Andrea, Felicia,De Rensis, Francesco,Goracci, Giampaolo
, p. 1167 - 1180 (2007/10/03)
The unreported title compound and its 2,6-di-O-benzyl derivative have been prepared from methyl β-D-galactopyranoside through a sequence involving the bisglycoside methyl 2,6-di-O-benzyl-5-C-methoxy-β-D-galactopyranoside 8, the precursor of L-arabino-hexo
