21673-26-7Relevant academic research and scientific papers
Anionic rearrangement of the germyl and silyl groups in dimethylammonium N-methylide and related compounds
Inoue, Sumie,Urayama, Shin'ichi,Sugiura, Hiroyo,Sato, Yoshiro
, p. 25 - 30 (2007/10/02)
The reaction of - and trimethylammonium iodides (3a and 3c) with n-butyllithium gives N-- and N-dimethylamines (5a and 5b), respectively.A mixture of 5a and 5b is obtained from the reaction of trimethylammonium iodide (3b).Use of lithium diisopropylamide in place of n-butyllithium gives the corresponding 1,1-bis(trimethylelemento)ethylenes (8a, 8b, and 8c) as the main products.
