21674-38-4Relevant academic research and scientific papers
REACTIONS OF PERFLUORONITRILES. II. INTERACTIONS WITH PHENYLPHOSPHINE
Paciorek, K. J. L.,Nakahara, J. H.,Kratzer, R. H.
, p. 269 - 288 (1985)
Treatment of perfluoro-n-octanonitrile with phenylphosphine gave tetraphenyltetraphosphine and a spectrum of reduction and interaction products.Fifteen compounds were identified.The imine, (Rf=C7F15) RfCH=NH, and the amine, RfCH2NH2, were the primary reduction products.Secondary phosphorus-free products, some formed following ammonia evolution, were the following: RfCH=NCH2Rf, RfCH2CH(NH2)Rf, RfC(=NH)N=CRf(NH2), RfCH2NHCRf(=NH), (RfCN)3, RfCH=NCRf=NCRf(=NH), RfCH2N=CRfNHCH2Rf, and RfCH2N=CRfNHCRf(=NH).Only three phosphorus-containing materials were definitely identified: RfCH(NH2)P(C6H5)H, RfCHN=CHRf, and RfC(=NH)P(C6H5)CRf(=NH).Depending on reaction conditions, specific phosphorus-containing compounds could be preferentially produced.All the structure assignments are based solely on mass spectral breakdown patterns, since pure compounds were not isolated.
REACTIONS OF PERFLUORONITRILES. I. INTERACTIONS WITH ANILINE
Paciorek, K. J. L.,Nakahara, J. H.,Kratzer, R. H.
, p. 241 - 250 (1985)
Perfluoro-n-octanonitrile was found to react with aniline both in the absence and presence of solvents.A spectrum of products was formed including tris(perfluoro-n-heptyl)-s-triazine, N-phenyl-perfluoro-n-octylamidine, and N'-(perfluoro-n-octylimidoyl)-N-phenyl-perfluoro-n-octylamidine, as well as the diphenyl analogues of the last two compounds.The reaction mechanisms, infrared and mass spectra are discussed.
