216754-79-9Relevant academic research and scientific papers
[Tl(OPPh3)2][Au(C6F5) 2]: The first extended unsupported gold-thallium linear chain
Crespo, Olga,Fernández, Eduardo J.,Jones, Peter G.,Laguna, Antonio,López-de-Luzuriaga, José M.,Mendía, Aránzazu,Monge, Miguel,Olmos, Elena
, p. 2233 - 2234 (1998)
Li[Au(C6F5)2] reacts with TlNO3 in the presence of OPPh3 affording a complex of stoichiometry [AuTl(C6F5)2-(OPPh3) 2]n, which presents different luminescence properties depending on the conditions and whose crystal structure reveals the existence of unsupported Au-Tl bonds forming a polymeric linear chain.
