216862-75-8Relevant academic research and scientific papers
cis-Disubstituted Cyclopropanes via Asymmetric Catalytic Cyclopropenation: Synthesis of Cyclopropyl-dehydroamino Acids and of Dictyopterene C′
Imogai, Hassan,Bernardinelli, Gerald,Graenicher, Christian,Moran, Mary,Rossier, Jean-Claude,Mueller, Paul
, p. 1754 - 1764 (2007/10/03)
The cyclopropenation of diethoxypropyne (1) with methyl diazoacetate in the presence of [Rh2{(2S)-mepy}4] (mepy = methyl 5-oxopyrrolidine-2-carboxylate) proceeds with >95% ee. The resulting cyclopropenecarboxylate 2 underwent stereos
