21692-54-6Relevant academic research and scientific papers
Heterogeneously catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes and monohydrosilanes by gold supported on oms-2
Yamaguchi, Kazuya,Wang, Ye,Oishi, Takamichi,Kuroda, Yoshiyuki,Mizuno, Noritaka
supporting information, p. 5627 - 5630 (2013/06/27)
Cross-dehydrogenative coupling of various terminal alkynes and monohydrosilanes efficiently proceeded in the presence of gold supported on OMS-2 (Au/OMS-2) using O2 as a terminal oxidant, affording the corresponding alkynylsilanes in moderate to high yields (see picture). The observed catalysis was truly heterogeneous, and the catalyst could be reused at least ten times without a significant loss of its high catalytic performance. Copyright
