21692-55-7Relevant academic research and scientific papers
Tuning the Selectivity of AuPd Nanoalloys towards Selective Dehydrogenative Alkyne Silylation
Wissing, Maren,Studer, Armido
supporting information, p. 5870 - 5874 (2019/03/21)
The cross-dehydrogenative coupling of terminal alkynes and hydrosilanes catalyzed by AuPd nanoalloys is described. Metal nanoparticles are readily prepared in 15 minutes from commercially available and cheap starting materials by using a photochemical app
Alkali metal-hydroxide-catalyzed C(sp)-H Bond silylation
Toutov, Anton A.,Betz, Kerry N.,Schuman, David P.,Liu, Wen-Bo,Fedorov, Alexey,Stoltz, Brian M.,Grubbs, Robert H.
supporting information, p. 1668 - 1674 (2017/02/10)
Disclosed is a mild, scalable, and chemoselective catalytic cross-dehydrogenative C-H bond functionalization protocol for the construction of C(sp)-Si bonds in a single step. The scope of the alkyne and hydrosilane partners is substantial, providing an entry point into various organosilane building blocks and additionally enabling the discovery of a number of novel synthetic strategies. Remarkably, the optimal catalysts are NaOH and KOH.
BASE-CATALYZED SILYLATION OF TERMINAL ALKYNE C-H BONDS
-
Paragraph 0168; 0175; 0195, (2016/05/02)
The present invention is directed to a mild, efficient, and general direct C(sp)-H bond silylation. Various embodiments includes methods, each method comprising or consisting essentially of contacting at least one organic substrate comprising a terminal a
