216980-80-2

Upstream product

• 17857-24-8 potassium tetracarbonylhydridoferrate 
• 50869-86-8 N,N'-diethyl-N,N'-diphenylphosphorodiamidous chloride 
• 50869-76-6 N,N',N''-triethyl-N,N',N''-triphenylphosphorous triamide 
• 17857-24-8 tetracarbonylhydridoferrate 

Downstream Products

• 216980-97-1 (((C₂H₅)(C₆H₅)N)2P(CH₃))Fe(CO)4 
• 216981-00-9 (((C₂H₅)(C₆H₅)N)2P(COCH₃))Fe(CO)4 

Relevant academic research and scientific papers

Synthesis and reactivity of [(R1R2N)2PH]Fe(CO)4 complexes. X-ray crystal structure of [(Ph2N)2PH]Fe(CO)4

KHFe(CO)4 reacts with tris(amino)phosphines by substitution at phosphorus leading to [bis(amino)phosphine]tetracarbonyliron complexes [(R1R2N)2PH]Fe(CO)4. The X-ray structure has been determined for R1=R2=Ph. Deprotonation of these complexes with KH affords stable potassium phosphidotetracarbonylferrates which can be alkylated or acylated at phosphorus.

Synthesis and reactivity of [(R1R2N)2PH]Fe(CO)4 complexes. X-ray crystal structure of [(Ph2N)2PH]Fe(CO)4

KHFe(CO)4 reacts with tris(amino)phosphines by substitution at phosphorus leading to [bis(amino)phosphine]tetracarbonyliron complexes [(R1R2N)2PH]Fe(CO)4. The X-ray structure has been determined for R1=R2=Ph. Deprotonation of these complexes with KH affords stable potassium phosphidotetracarbonylferrates which can be alkylated or acylated at phosphorus.