2170-08-3Relevant articles and documents
Experimental and theoretical studies of magnetic exchange in silole-bridged diradicals
Roques, Nans,Gerbier, Philippe,Schatzschneider, Ulrich,Sutter, Jean-Pascal,Guionneau, Philippe,Vidal-Gancedo, Jose,Veciana, Jaume,Rentschler, Eva,Guerin, Christian
, p. 5547 - 5562 (2006)
Five bis(tert-butylnitroxide) diradicals connected by a silole (7a-d) or a thiophene (12) ring as a coupler were studied. Compound 12 crystallizes in the orthorhombic space group Pna21 with a = 20.752(5), b = 5.826(5), and c = 34.309(5) A. X-ra
Electrochemiluminescence Platforms Based on Small Water-Insoluble Organic Molecules for Ultrasensitive Aqueous-Phase Detection
Han, Zhengang,Yang, Zhaofan,Sun, Heshui,Xu, Yali,Ma, Xiaofang,Shan, Duoliang,Chen, Jing,Huo, Shuhui,Zhang, Zhen,Du, Peiyao,Lu, Xiaoquan
, p. 5915 - 5919 (2019)
Highly efficient detection in the aqueous phase for water-insoluble organic molecule probes is challenging. The bright aggregated-state electrochemiluminescence (ECL) of 1,1-disubstituted 2,3,4,5-tetraphenylsiloles by a co-reactant approach was discovered
Catalytic Decarboxylation of Silyl Alkynoates to Alkynylsilanes
Aoyagi, Keiya,Choi, Jun-Chul,Kawatsu, Takahiro,Matsumoto, Kazuhiro,Nakajima, Yumiko,Sato, Kazuhiko
supporting information, (2020/09/15)
Herein, we describe a decarboxylative approach to the preparation of alkynylsilanes. Treatment of a silyl alkynoate in N,N-dimethylformamide (DMF) at 80 °C in the presence of catalytic amounts of CuCl and PCy3 produced the corresponding alkynylsilane in excellent yield. The copper-catalyzed decarboxylation proceeded smoothly with low catalyst loadings (0.5 mol % of CuCl and 1.0 mol % of PCy3) under mild reaction conditions and is easily scalable to gram quantities.
METHOD FOR PRODUCING ORGANOSILICON COMPOUND USING HALOSILANE AS RAW MATERIAL
-
Paragraph 0044-0045; 0055, (2019/12/10)
PROBLEM TO BE SOLVED: To provide a novel method for producing an organosilicon compound. SOLUTION: The method for producing an organosilicon compound includes a reaction step (I) of reacting a halosilane represented by formula (a) with a compound containing a hydrocarbon group represented by formula (b) in the presence of an organic base to generate an organosilicon compound represented by formula (c). (In the formula (I), n is an integer of 0-3; each R1 independently represents a hydrogen atom or a C1-20 hydrocarbon group which may contain a heteroatom; X represents a bromo group (-Br) or a chloro group (-Cl); and R2 represents a compound containing a hydrocarbon group.) SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2020,JPOandINPIT
Water-soluble AIE luminogens for monitoring and retardation of fibrillation of amyloid proteins
-
Page/Page column 67, (2016/04/20)
Compounds that exhibit aggregation induced emission (AIE), and more particularly to water-soluble conjugated polyene compounds that exhibit aggregation induced emission. The conjugated polyene compounds can be used as bioprobes for DNA detection, G-quadru
Siloles and acetenyl aromatics copolymers: Synthesis, characterization and photophysical properties
He, Zhenhua,Lai, Guoqiao,Li, Zhifang,Yuan, Xiao,Shen, Yongjia,Wang, Chengyun
, p. 550 - 558 (2015/05/27)
Two copolymers, poly(1,1-dimethyl-3,4-diphenylsilole-alt-N-hexyl-3,6-diethynylcarbazole) (PS-DyCz) and poly(1,1-dimethyl-3,4-diphenylsilole-alt-2,7-diethynyl-9,9′-dihexylfluorene) (PS-DyF), were synthesized by Sonogashira coupling reaction of 2,5-dibromo-
Iridium-promoted conversion of chlorosilanes to alkynyl derivatives in a one-pot reaction sequence
Kownacki, Ireneusz,Orwat, Bartosz,Marciniec, Bogdan
supporting information, p. 3051 - 3059 (2014/07/08)
By making use of the catalytic potential of the iridium system [{Ir(μ-Cl)(CO)2}2]/NEt(i-Pr)2 in the synthesis of silyl-functionalized alkynes via silylative coupling of terminal alkynes/diynes with iodosilanes, we propose
Grignard metathesis polymerization and properties of 1,1-disubstituted-2,5- dibromo-3,4-diphenylsiloles
Park, Young Tae
, p. 1825 - 1831 (2014/07/07)
Grignard metathesis polymerizations of 1,1-disubstituted-2,5-dibromo-3,4- diphenylsiloles such as 1,1-dimethyl-2,5-dibromo-3,4-diphenylsilole, 1,1-diethyl-2,5-dibromo-3,4-diphenylsilole, 1,1-diisopropyl-2,5-dibromo-3,4- diphenylsilole, and 1,1-dihexyl-2,5
Biocompatible Nanoparticles with Aggregation Induced Emission Characteristics as Fluorescent Bioprobes and Methods of Using the Same for In Vitro and In Vivo Imaging
-
Page/Page column, (2014/11/13)
The development of fluorescent bioprobes comprising organic fluorescent compounds that exhibit aggregation induced emission (AIE) properties, methods of producing the same, and their practical applications for in vitro and in vivo bioimaging.
Conjugation versus rotation: Good conjugation weakens the aggregation-induced emission effect of siloles
Chen, Bin,Nie, Han,Lu, Ping,Zhou, Jian,Qin, Anjun,Qiu, Huayu,Zhao, Zujin,Tang, Ben Zhong
supporting information, p. 4500 - 4503 (2014/04/17)
Incorporation of polycyclic aromatic hydrocarbons into siloles enhances their light emission in solutions but lowers emission efficiency in the aggregated state. The competitive interaction between conjugation and rotation is thus studied. This journal is