2170-08-3Relevant articles and documents
Experimental and theoretical studies of magnetic exchange in silole-bridged diradicals
Roques, Nans,Gerbier, Philippe,Schatzschneider, Ulrich,Sutter, Jean-Pascal,Guionneau, Philippe,Vidal-Gancedo, Jose,Veciana, Jaume,Rentschler, Eva,Guerin, Christian
, p. 5547 - 5562 (2006)
Five bis(tert-butylnitroxide) diradicals connected by a silole (7a-d) or a thiophene (12) ring as a coupler were studied. Compound 12 crystallizes in the orthorhombic space group Pna21 with a = 20.752(5), b = 5.826(5), and c = 34.309(5) A. X-ra
Electrochemiluminescence Platforms Based on Small Water-Insoluble Organic Molecules for Ultrasensitive Aqueous-Phase Detection
Han, Zhengang,Yang, Zhaofan,Sun, Heshui,Xu, Yali,Ma, Xiaofang,Shan, Duoliang,Chen, Jing,Huo, Shuhui,Zhang, Zhen,Du, Peiyao,Lu, Xiaoquan
, p. 5915 - 5919 (2019)
Highly efficient detection in the aqueous phase for water-insoluble organic molecule probes is challenging. The bright aggregated-state electrochemiluminescence (ECL) of 1,1-disubstituted 2,3,4,5-tetraphenylsiloles by a co-reactant approach was discovered
METHOD FOR PRODUCING ORGANOSILICON COMPOUND USING HALOSILANE AS RAW MATERIAL
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Paragraph 0044-0045; 0055, (2019/12/10)
PROBLEM TO BE SOLVED: To provide a novel method for producing an organosilicon compound. SOLUTION: The method for producing an organosilicon compound includes a reaction step (I) of reacting a halosilane represented by formula (a) with a compound containing a hydrocarbon group represented by formula (b) in the presence of an organic base to generate an organosilicon compound represented by formula (c). (In the formula (I), n is an integer of 0-3; each R1 independently represents a hydrogen atom or a C1-20 hydrocarbon group which may contain a heteroatom; X represents a bromo group (-Br) or a chloro group (-Cl); and R2 represents a compound containing a hydrocarbon group.) SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2020,JPOandINPIT