217185-22-3

Basic information

• Product Name: Benzene, [1-methyl-1-(2-propenyloxy)-2-propynyl]-
• CAS NO: 217185-22-3
• Molecular Formula: C13H14O
• Molecular Weight: 186.254
• Mol File: 217185-22-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [1-methyl-1-(2-propenyloxy)-2-propynyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [1-methyl-1-(2-propenyloxy)-2-propynyl]-(217185-22-3)
• EPA Substance Registry System: Benzene, [1-methyl-1-(2-propenyloxy)-2-propynyl]-(217185-22-3)

Safety Data

• Hazardous Substances Data: 217185-22-3(Hazardous Substances Data)

Upstream product

• 127-66-2 2-Phenyl-3-butyn-2-ol 
• 106-95-6 allyl bromide 

Downstream Products

• 1260370-53-3 C₁₃H₁₄O 

Relevant articles and documents

Ring-Closing Enyne Metathesis of Terminal Alkynes with Propargylic Hindrance

The ring closing enyne metathesis of substrates with propargylic hindrance was investigated, revealing the successful combination of the Stewart-Grubbs catalysts and microwave heating sometimes up to 170 C for oxacycles. Medium-sized rings were obtained from terminal alkynes previously reputed as reluctant substrates. This unmatched combination was applied to the synthesis of carbocycles and oxacycles. In addition, this is the first report on the use of the Stewart Grubbs catalyst in ring closing enyne metatheses. (Figure Presented).

A new cycloisomerisation catalyst of enynes: One-step synthesis of 3,4- dialkylidenetetrahydrofurans from allyl propargyl ethers

The precatalyst RuCl(cod)C5Me5 in the presence of acetic acid or ethanol allows the selective one-step cycloisomerisation of allyl propargyl ethers into 3,4-dialkylidenetetrahydrofurans.