217315-29-2Relevant academic research and scientific papers
Synthesis of manganese tricarbonyl cationic complexes of ferrocenyl substituted arenes via a manganese tricarbonyl cation transfer reaction
Kim, Jung Eun,Son, Seung Uk,Lee, Su Seong,Chung, Young Keun
, p. 229 - 234 (2008/10/08)
Manganese tricarbonyl cations of ferrocenyl substituted arenes were synthesized by the reaction of [(naphthalene)Mn(CO)3]BF4 with the corresponding arenes in dichloromethane. When the arenes are phenylferrocene, 4-methylphenyl-ferrocene,2,6-dimethylphenyl-ferrocene, 2,4,6-trimethylphenyl-ferrocene, trans-(4-methylstyryl)-ferrocene, or trans-(2,4,6-trimethylstyryl)-ferrocene, the diiron compounds [(Fc-arene)FeCp]+ and [(Fc-arene)Fe(C5H4-arene)]+ are obtained as side-products. One of the diiron compounds was characterized by X-ray crystallography.
