217315-74-7Relevant articles and documents
Preparation of hexacarbonyldicobalt-complexed 1,3-dioxa-2-silacycloheptynes
Brook, Michael A.,Urschey, J?rg,Stradiotto, Mark
, p. 5342 - 5346 (2008/10/08)
The reaction between 2-butyne-1,4-diol-hexacarbonyldicobalt and a series of dichlorodi-alkylsilanes (R = Me, Et, CH=CH2, and Ph) in the presence of triethylamine results in the formation of the corresponding cobalt-complexed 1,3-dioxa-2-silacycloheptynes, 3-7, as the major products. Complexed silacyclononynes, 8 and 9, and a spirocyclic analogue 10, have also been prepared and characterized. The solid-state structures of 3 and 10 have been determined by X-ray diffraction studies. ? 1998 American Chemical Society.