21746-98-5Relevant academic research and scientific papers
OXIDATIVE DEPROTONATION OF CARBONYL COMPOUNDS BY Fe(III) SALTS
Citterio, Attilio,Cerati, Anna,Sebastiano, Roberto,Finzi, Claudia,Santi, Roberto
, p. 1289 - 1292 (2007/10/02)
Iron (III) salts (perchlorate and nitrate nonahydrate) in acetonitrile or acetic anhydride at 0-50 deg C oxidize the α-position of malonic esters efficiently via the corresponding radicals.In the presence of olefins and aromatics, inter- and intramolecular free radical chain or oxidative additions are observed.
