217633-08-4Relevant academic research and scientific papers
Reaction control in synthetic organic photochemistry: Switching between [5+2] and [2+2] Modes of Cycloaddition
Roscini, Claudio,Cubbage, Kara L.,Berry, Malcolm,Orr-Ewing, Andrew J.,Booker-Milburn, Kevin I.
supporting information; experimental part, p. 8716 - 8720 (2010/03/01)
Split personality: Reaction conditions that enable powerful control over the mode of photocycloaddition in maleimides have been developed. Direct irradiation favors the [5+2] mode whereas sensitized irradiation allows a complete switch to the [2+2] mode (see scheme; TBS=tertbutyldimethylsilyl).
Mild conditions for Pd-catalyzed carboamination of N-protected hex-4-enylamines and 1-, 3-, and 4-substituted pent-4-enylamines. Scope, limitations, and mechanism of pyrrolidine formation
Bertrand, Myra Beaudoin,Neukom, Joshua D.,Wolfe, John P.
supporting information; experimental part, p. 8851 - 8860 (2009/04/11)
(Chemical Equation Presented) The use of the weak base Cs 2CO3 in Pd-catalyzed carboamination reactions of N-protected γ-aminoalkenes with aryl bromides leads to greatly increased tolerance of functional groups and alkene substitutio
