21764-32-9Relevant academic research and scientific papers
Total synthesis of paniculide a from D-glucose
Amano, Seiji,Takemura, Noriaki,Ohtsuka, Masami,Ogawa, Seiichiro,Chida, Noritaka
, p. 3855 - 3870 (2007/10/03)
The chiral total synthesis of paniculide A (1), a highly oxygenated sesquiterpene possessing a bisabolane skeleton, starting from D-glucose is described. The two different approaches, both involved Ferrier's carbocyclization reaction to construct the cycl
Total synthesis of (+)-paniculide A via a catalytic asymmetric Diels-Alder reaction of a 3-borylpropenoic acid derivative
Yamamoto,Narasaka
, p. 3327 - 3333 (2007/10/02)
(+)-Paniculide A, a highly oxidized sesquiterpene, has been synthesized enantioselectively starting from a cycloadduct, which was prepared from 3-(3-borylpropenoyl)-1,3-oxazolidin-2-one and 1-acetoxy-3-methyl-1,3-butadiene by a catalytic asymmetric Diels-
On the Role of Leucine in Terpenoid Metabolism
Anastasis, Panayiotis,Freer, Isabel,Overton, Karl H.,Picken, Douglas,Rycroft, David S.,Singh, Sheo Bux
, p. 2427 - 2436 (2007/10/02)
Incorporation of -, -, (4R)-- and (4S)--leucines into paniculide by tissue cultures of Andrographis paniculata shows that (a) (3S)-3-hydroxy-3-methylglutaryl-CoA (HMG-CoA) from leucine breakdown is not incorporated direct into
