217652-51-2Relevant academic research and scientific papers
Synthesis of dibenzodiynes: Exceptionally easy formation of a chrysene biradical
Rodríguez,Rodríguez,López,Castedo,Domínguez,Saá
, p. 1282 - 1284 (2007/10/03)
The new dibenzodiynes 1 and 2 have been synthesized using a Nozaki-Hiyama-Kishi reaction as the key step. Treatment of dibenzodiynone 2 with base at -50°C afforded an enyne-cumulene intermediate that underwent a regioselective cycloaromatization via a chrysene biradical.
