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Ethenyl(diphenyl)phosphane sulfide, with the molecular formula C14H13PS, is a yellowish-white solid that is insoluble in water but soluble in organic solvents. It is a chemical compound known for its potential applications in various fields.

21776-15-8

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21776-15-8 Usage

Uses

Used in Organic Synthesis:
Ethenyl(diphenyl)phosphane sulfide is used as a reagent in organic synthesis, particularly for the preparation of organophosphorus compounds. Its unique properties make it a valuable component in the creation of various chemical products.
Used in Plastics Industry:
As a stabilizer for PVC, ethenyl(diphenyl)phosphane sulfide plays a crucial role in enhancing the durability and stability of plastic materials, thereby improving their performance and longevity.
Used in Flame Retardancy:
Ethenyl(diphenyl)phosphane sulfide is recognized for its potential use as a flame retardant. It is being researched for its possible applications in fire-resistant materials, which could contribute to increased safety in various industries.
Used in Pharmaceutical Research:
Due to its antibacterial and antitumor properties, ethenyl(diphenyl)phosphane sulfide is being studied for potential use in medicine. Its ability to combat infections and inhibit tumor growth makes it a promising candidate for further research and development in the medical field.
However, it is important to handle ethenyl(diphenyl)phosphane sulfide with caution, as it may be irritant to the skin, eyes, and respiratory system. Proper safety measures should be taken to minimize any potential risks associated with its use.

Check Digit Verification of cas no

The CAS Registry Mumber 21776-15-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,1,7,7 and 6 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 21776-15:
(7*2)+(6*1)+(5*7)+(4*7)+(3*6)+(2*1)+(1*5)=108
108 % 10 = 8
So 21776-15-8 is a valid CAS Registry Number.

21776-15-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name ethenyl-diphenyl-sulfanylidene-λ<sup>5</sup>-phosphane

1.2 Other means of identification

Product number -
Other names diphenylvinylphosphine sulphide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:21776-15-8 SDS

21776-15-8Relevant academic research and scientific papers

Mass spectrometry and quantum chemical studies of the reaction of divinyl telluride with secondary phosphine sulfides: Synthesis of adducts

Gusarova, Nina K.,Chernysheva, Nataliya A.,Klyba, Lyudmila V.,Shagun, Vladimir A.,Yas'Ko, Svetlana V.,Smirnov, Vladimir I.,Trofimov, Boris A.

, p. 126 - 132 (2013/10/01)

Mass spectrometry and quantum chemical studies of the reaction of divinyl telluride with diphenylphosphine sulfide have been carried out. Reaction proceeds under radical initiation (AIBN, 63-68 C, 2.5 h, THF, reactants molar ratio = 1:1) to afford the ant

Reaction of divinyl telluride with secondary phosphine chalcogenides

Gusarova,Chernysheva,Yas'ko,Klyba,Trofimov

experimental part, p. 2506 - 2509 (2012/04/10)

Divinyl telluride reacted with 2 equiv of diphenylphosphine sulfide in the presence of AIBN as radical initiator (63-68°C) to give the corresponding anti-Markovnikov adduct in 68% yield with high regioselectivity. Treatment of the addition product with aqueous hydrogen peroxide at room temperature afforded 71% of vinyldiphenylphosphine oxide. Radical addition of diphenylphosphine selenide to divinyl telluride (AIBN, 63-68°C) led to the formation of 1,1,3,3-tetraphenyldiphosphoxane 1,3-diselenide in 82% yield. Pleiades Publishing, Ltd., 2011.

Highly atom-economic one-pot formation of three different C-P bonds: General synthesis of acyclic tertiary phosphine sulfides

Baccolini, Graziano,Boga, Carla,Mazzacurati, Marzia

, p. 4774 - 4777 (2007/10/03)

The reaction of benzothiadiphosphole 1 with an equimolar mixture of R 1MgBr and R2MgBr gave intermediate A′, which, after only 4-5 min, was treated with an equimolar amount of R3MgBr, giving the asymmetric phosphine PR1R2R3 in 45% overall yield (75-80% yield when R1 = R2 and 85-90% yield when R1 = R2 = R3) and the byproduct 6 in 90% yield. The treatment of 6 with PCl3 quantitatively regenerates the starting reagent 1. Treatment of the phosphines with elemental sulfur gave the corresponding sulfides.

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