217814-47-6

Basic information

• Product Name: CH₃OC₆H₄CH₂O₂Co(C₄H₇N₂O₂)2(C₅H₅N)
• CAS NO: 217814-47-6
• Molecular Weight: 521.476
• Mol File: 217814-47-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: CH₃OC₆H₄CH₂O₂Co(C₄H₇N₂O₂)2(C₅H₅N)(CAS DataBase Reference)
• NIST Chemistry Reference: CH₃OC₆H₄CH₂O₂Co(C₄H₇N₂O₂)2(C₅H₅N)(217814-47-6)
• EPA Substance Registry System: CH₃OC₆H₄CH₂O₂Co(C₄H₇N₂O₂)2(C₅H₅N)(217814-47-6)

Safety Data

• Hazardous Substances Data: 217814-47-6(Hazardous Substances Data)

Upstream product

• 42194-65-0 4-methoxybenzyl Co(III)(dmgH)2py 
• 80937-33-3 oxygen 
• 217814-37-4 C₄H₃SCH₂Co(C₂(C₆H₅)2HN₂O₂)2(C₅H₅N) 

Relevant articles and documents

Organocobaloximes: Synthesis, oxygen insertion and kinetics

A total of 27 organocobaloximes have been synthesised and characterized with three different dioxime ligands, dmgH, chgH and dpgH. Many of the chgH and all the dpgH complexes have been synthesised for the first time. The insertion of molecular oxygen into these organocobaloximes, RCoIII(L2)B [L=dmgH, chgH and dpgH) under thermal and photochemical conditions have been studied. Kinetic studies at ambient temperature under irradiation show that the rate of insertion depends upon the nature of R, L, B and the solvent. The rate follows the order dpgH>chgH>dmgH; Naphthyl>heteroaromaticmethyl>benzyl; piperidine>morpholine>γ-picoline>pyridine>2- bromopyridine>2-acetylpyridine; and the rates are faster in acetonitrile than in acetone and chloroform. In methanol, the benzylic cobaloximes exist as an equilibrium mixture of solvated penta-coordinated and hexa-coordinated species and in chloroform these exist as hexa-coordinated species.