21859-00-7Relevant academic research and scientific papers
Electroreduction of tetra-coordinate phosphonium derivatives; One-pot transformation of triphenylphosphine oxide into triphenylphosphine
Kuroboshi, Manabu,Yano, Tomotake,Kamenoue, Shogo,Kawakubo, Hiromu,Tanaka, Hideo
, p. 5825 - 5831 (2011)
Electroreduction of triphenylphosphine dichloride in acetonitrile was performed successfully in an undivided cell fitted with an aluminium sacrificial anode and a platinum cathode, wherein Al3+, which was electrogenerated at the anode would react as a Lewis acid with triphenylphosphine dichloride to afford tetra-coordinate chlorotriphenylphosphonium species and subsequent two-electron reduction at the cathode would give triphenylphosphine. One-pot transformation of triphenylphosphine oxide to triphenylphosphine was achieved successfully by the treatment of triphenylphosphine oxide with oxalyl chloride and subsequent electroreduction. In a similar manner, some tetra-coordinate triphenylphosphonium species derived from triphenylphosphine oxide were reduced electrochemically to triphenylphosphine in moderate yields.
A Synthetic Model of Enzymatic [Fe4S4]-Alkyl Intermediates
Brown, Alexandra C.,Suess, Daniel L. M.,Thompson, Niklas B.,Ye, Mengshan
, (2019)
Although alkyl complexes of [Fe4S4] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to
