2187-85-1Relevant academic research and scientific papers
THERMOLYSE DES CARBONATES D'ARYLE INITIEE PAR LES BASES : I-MECANISME PAR SNAR DANS LE CAS DES CARBONATES D'ARYLE PORTEURS DE GROUPES ELECTRO-ATTRACTEURS IDENTIQUES.
Jost, Philippe,Forestiere, Alain,Sillion, Bernard,Le Perchec, Pierre
, p. 4311 - 4314 (2007/10/02)
The base-initiated thermolysis of diaryl carbonates leads to diaryl ethers.Kinetics evidences (Ea= 26 kcal.mole-1 )are given, showing that reaction proceeds via SNAr mechanism.Phenoxide is recognised as the active species.
