21907-37-9Relevant academic research and scientific papers
Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework
Agou, Tomohiro,Wada, Nao,Fujisawa, Kiyoshi,Hosoya, Takaaki,Mizuhata, Yoshiyuki,Tokitoh, Norihiro,Fukumoto, Hiroki,Kubota, Toshio
, p. 9105 - 9114 (2018)
Cu(I), Ag(I), and Au(I) complexes of monophosphine or bisphosphine ligands based on the 3,3,4,4,5,5-hexafluorocyclopentene skeleton were synthesized and structurally characterized by X-ray crystallographic analysis. The electron-withdrawing nature of these polyfluorinated phosphines was experimentally revealed via UV/vis absorption studies and crystal structure analysis. Successful catalytic application of the Au(I) complex for alkyne hydration reactions was investigated.
