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(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE is a complex organic compound with a chromium(III) center, featuring a cyclohexanediamine backbone and two bulky 3,5-di-t-butylsalicylidene substituents. This molecule is characterized by its chiral centers at the 1 and 2 positions, which give it a specific stereochemistry. The compound is likely to have unique chemical and physical properties due to its structure, making it potentially useful in various applications.

219143-92-7

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219143-92-7 Usage

Uses

1. Used in Catalyst Applications:
(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE is used as a catalyst for [application reason] due to its unique structure and electronic properties. The chiral nature of the molecule may also make it suitable for asymmetric catalysis, where the stereochemistry of the product is controlled by the stereochemistry of the catalyst.
2. Used in Coordination Chemistry:
In the field of coordination chemistry, (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE is used as a building block for the synthesis of more complex metal-organic frameworks (MOFs) or as a ligand in the formation of metal complexes with specific properties, such as magnetism or luminescence.
3. Used in Pharmaceutical Applications:
Given the potential for (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE to interact with biological systems, (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE may be used as a starting point for the development of new pharmaceuticals, particularly those targeting metalloenzymes or requiring metal-based catalysts for their biological activity.
4. Used in Material Science:
The unique structure of (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE may also find applications in material science, where it could be used to create novel materials with specific properties, such as improved mechanical strength, thermal stability, or optical characteristics.
5. Used in Analytical Chemistry:
The compound's distinct structure and potential for chiral recognition make it a candidate for use in analytical chemistry, particularly in the development of chiral stationary phases for high-performance liquid chromatography (HPLC) or as a chiral selector in capillary electrophoresis.
6. Used in Environmental Applications:
(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE may also be employed in environmental applications, such as the remediation of chromium-contaminated sites or the development of new methods for the detection and quantification of chromium species in the environment.

Reaction

Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides. Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions. Catalyst for copolymerization of CO2 and epoxides. Catalyst for enantioselective alkylation of tributyltin enolates. Enantioselective addition of Me2Zn to aldehydes. Enantioselective intramolecular addition of tertiary enamides to ketones. Asymmetric iodocyclization. Catalytic intermolecular linear allylic C-H animation. Cocatalyst for enantioselective ring opening of epoxides with fluoride.

Check Digit Verification of cas no

The CAS Registry Mumber 219143-92-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,1,9,1,4 and 3 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 219143-92:
(8*2)+(7*1)+(6*9)+(5*1)+(4*4)+(3*3)+(2*9)+(1*2)=127
127 % 10 = 7
So 219143-92-7 is a valid CAS Registry Number.

219143-92-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis [4,6-bis(2-methyl-2-propanyl)phenol] - trichlorochromium (1:1)

1.2 Other means of identification

Product number -
Other names Cr-Salen-Cy

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:219143-92-7 SDS

219143-92-7Upstream product

219143-92-7Downstream Products

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