21919-29-9

Upstream product

• 15613-31-7 mer-IrCl₃(PMe₂Ph)3 
• 12099-72-8 mer-(PMe₂Ph)3H-trans-Cl₂Ir(III) 

Downstream Products

• 117477-34-6 trans,mer-IrCl₂(NCS)(PMe₂Ph)3 
• 106587-16-0 {(PMe₂Ph)3Cl₂Ir(H₂O)}ClO₄ 
• 15613-30-6 trans,mer-IrCl₂I(PMe₂Ph)3 
• 32475-35-7 trans,mer-IrClI₂(PMe₂Ph)3 
• 79469-85-5 dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C₁P)iridium(III) 
• 55493-03-3 IrCl₂(C₆F₅CN)(P(CH₃)2C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=(IrCl₂(C₆F₅CN)(P(CH₃)2C₆H₅)3)PF₆ 
• 105817-29-6 IrCl₂(CO)(P(CH₃)2C₆H₅)3⁽¹⁺⁾*BF₄^(1-)=[IrCl₂(CO)(P(CH₃)2C₆H₅)3][BF₄] 
• 105881-10-5 IrCl₂(CO)(P(CH₃)2C₆H₅)3⁽¹⁺⁾*ClO₄^(1-)=[IrCl₂(CO)(P(CH₃)2C₆H₅)3][ClO₄] 
• 12099-72-8 mer-(PMe₂Ph)3H-trans-Cl₂Ir(III) 
• 105784-11-0 [IrCl₂(HCO₂)(P(CH₃)2C₆H₅)3] 

Relevant academic research and scientific papers

The Structures of the fac and mer Isomers of Trichlorotrisiridium(III)

The structure of the facial isomer of trichlorotrisiridium(III) has been determined, and that of the meridional isomer has been redetermined. fac-IIICl3(PMe2Ph)3>(1) crystallizes in space group Ia with a=16.198(2), b=14.923(2), c=22.024(2) Angstroem, β=96.37(2) deg, Z=8. mer-IIICl3(PMe2Ph)3>(2) crystallizes in space group P21/n with a=10.814(1), b=38.894(3), c=13.663(1) Angstroem, β=107.15(1) deg, Z=8.The structures were refined to R=0.025 and 0.031 .Metal-ligand distances in (1) are Ir-Cl 2.456(2)-2.468(2) Angstroem (trans to P) and Ir-P 2.285(2)-2.295(2) Angstroem (trans to Cl).Metal-ligand distances in (2) do not differ significantly from those reported earlier but are more precise and reveal the existence of small differences between chemically equivalent bonds due to inequivalence of intramolecular non-bonding interactions.Values from this experiment are: Ir-Cl 2.434(1)-2.439(1) Angstroem (trans to P) and 2.359(1)-2.368(1) Angstroem (trans to Cl), Ir-P 2.278(1)-2.282(1) Angstroem (trans to Cl) and 2.363(1)-2.384(1) Angstroem (trans to P).