219295-97-3Relevant articles and documents
Access to 2,4-Dien-6-ynoic Acid Esters Using Selenium Chemistry. Formal Synthesis of Z,Z-Dodeca-3,6-dien-1-ol Trail Pheromone Mimic of the Subterranian Termite
Vasil'ev, Andrei A.,Engman, Lars,Serebryakov, Edward P.
, p. 706 - 707 (2007/10/03)
Esters of 2,4-dien-6-ynoic acids were prepared from terminal acetylenes by lithiation, 1,2-addition to acrolein, orthoester Claisen-Johnson rearrangement and α-(4-methoxyphenyl)selenation/oxidative elimination to introduce the α,β-unsaturation.