219313-13-0Relevant articles and documents
Synthesis and glycosidic coupling reaction of substituted 2,6-dioxabicyco[3.1.1] heptanes: 1,3-anhydro-2-azido-4,6-di-O-benzyl-2-deoxy-β-D-mannopyranose
Yang, Guangbin,Kong, Fanzuo
, p. 77 - 83 (2007/10/03)
The title 1,3-anhydro sugar was synthesized from methyl α-D-glucopyranoside. The key intermediate for the synthesis was 3-O-acetyl-2-azido-4,6-di-O-benzyl-2-deoxy-α-D-mannopyranosyl chloride (11) which was transformed into the target compound by ring closure with potassium tert-butoxide. Copyright (C) 1998 Elsevier Science Ltd.