21932-98-9

Upstream product

• 700-57-2 1-adamantanol 
• 700-58-3 2-Adamantanone 

Downstream Products

• 66483-55-4 (+)-(1S,5R)-endo-(3(R)-bicyclo<3.3.1>non-6-enyl) methyl ketone 
• 19213-96-8 4^e-chloroadamantan-2-one 
• 19213-96-8 4^a-chloroadamantan-2-one 
• 51020-64-5 4-Hydroxyadamantan-2-on 
• 19213-96-8 4-chloro^eq-adamantan-2-one 
• 19213-96-8 4-chloro^ax-adamantan-2-one 
• 66483-55-4 (+)-(1S,3R,5R)-endo-(3-bicyclo<3.3.1>non-6-enyl) methyl ketone 
• 19489-16-8 (1R,3r,5S)-bicyclo[3.3.1]nonane-3-carboxylic acid 
• 19489-17-9 3α-Methoxycarbonyl-1α(H),5α(H)-bicyclo<3.3.1>nonan 
• 38773-21-6 2-phenyladamantan-1-ol 
• 19740-34-2 2,2-dimethyladamantane 
• 84063-98-9 endo-bicyclo<3.3.1>non-6-ene-3-(methyl-d2) tosylate 
• 30860-11-8 3-endo-<(tosyloxy)methyl>bicyclo<3.3.1>non-6-ene 

Relevant academic research and scientific papers

Eu(FOD)3 INDUCED SHIFTS OF ALKYL SUBSTITUTED ADAMANTANONES AND MOLECULAR GEOMETRIES OF THE ADDUCTS

The geometries of adducts of europium tris(fod) and a series of alkyl-substituted adamantanones have been determined with the use of lanthanide induced 1H shift measurements.The position of the Eu(III) cation relative to the substrate ligand appears to be strongly dependent upon steric interactions between the fod ligands and the alkyl groups in the substrate.The alkyl substitution causes distortions from the otherwise linear C-O-Eu array.In general the Eu(III) cation moves away from the alkyl substituents.

5-oxo-4-oxa-5-homocitric adamantanedicarboxylic-2-ol manufacturing method

A method for manufacturing 5-oxo-4-oxa-5-homoadmantane-2-ol expressed by the formula (I) by reacting 5-oxo-4-oxa-5-homoadmantane expressed by the formula (A) with hydrogen peroxide in the presence of sulfuric acid.

Practical preparation methods for highly active azaadamantane-nitroxyl- radical-type oxidation catalysts

We have recently disclosed that a less hindered class of nitroxyl radicals, i.e., 2-azaadamantan-N-oxyl (AZADO), 1-Me-AZADO, and 9-azabicyclo[3.3.1]nonan- N-oxyl (ABNO), exhibit marked catalytic activity for the oxidation of alcohols with the aid of environmentally friendly oxidants, offering a green and sustainable option for current alcohol oxidation. Encouraged by their outstanding catalytic performance, we envisioned the development of scalable routes to these radicals that could be extended to the commercialization of these radicals for benchtop use as well as for industrial use as optional reagents that complement TEMPO, the flagship compound of stable nitroxyl radicals. We herein describe short and reproducible preparation methods for AZADO and 1-Me-AZADO, featuring an efficient construction of the 2-azaadamantane skeleton. 1 Introduction 2 1-Me-AZADO and AZADO: First-Generation Syntheses 3 Second-Generation Synthesis of 1-Me-AZADO 4 Synthetic Venture towards 2-Azaadamantane: Second-Generation Synthesis of AZADO 5 Conclusion. Georg Thieme Verlag Stuttgart.

SUBSTITUTED-QUINOXALINE-TYPE BRIDGED-PIPERIDINE COMPOUNDS AND THE USES THEREOF

The invention relates to Substituted-Quinoxaline-Type Bridged-Piperidine Compounds, compositions comprising an effective amount of a Substituted-Quinoxaline- Type Bridged-Piperidine Compound and methods to treat or prevent a condition, such as pain, compr