21942-04-1Relevant articles and documents
REACTION OF METHYL AND PHENYL PICRATES WITH NUCLEOPHILES
Artamkina, G. A.,Egorov, M. P.,Beletskaya, I. P.,Reutov, O.A.
, p. 25 - 31 (2007/10/02)
The reactions of 2,4,6-trinitroanisole with various nucleophiles Me3SnM, Me3SiLi, BuLi, Me4NBBu4, PhMgI, CN-, lithium (potassium) succinimide, F-, Cl-, Br-, SCN-, NO2-, NO3-, HCO3-, PhSO2-,AcO-, S2- were investigated.It was found that the final products are the picrate and the corresponding methyl derivatives.The formation of intermediate ? complexes was detected in a series of the reactions (Me3SnLi, potassium succinimide, Bu4B-, CN-, NO2-, PhSO2-).Possible mechanisms for the reaction are examined.Reactions of 2,4,6-tricyanoanisole and phenyl picrate with certain nucleophiles were also investigated.