219488-97-8Relevant articles and documents
Engineering of aggregation-induced emission luminogens by isomeric strategy to achieve high-performance optoelectronic device
Wen, Lili,Zang, Chunxiu,Gao, Ying,Tao, Yanli,Li, Guangfu,Shan, Guogang,Sun, Haizhu,Xie, Wenfa,Su, Zhongmin
, (2020)
Achieving non-doped organic light-emitting diodes (OLEDs) with high electroluminescent (EL) performance is essential for both illumination source and display applications. A source of this difficulty is the aggregation-induce quenching effect of emitters
Triptycene-scaffolded tetraphenylethylenes with irregular temperature-dependence AIE
Wang, Lijun,Li, Wenjie,Wang, Zhaoxia,Luo, Qianfu
, p. 439 - 443 (2019)
A series of new tetraphenylethylene monomer, dimer and three-dimensional trimer based triptycene-bridged triphenylethenes has been constructed. Their structures were clearly confirmed and the irregular fluorescent behaviors at different temperatures and s
Opposite ESIPT characteristic of two AIE-active isomers with different linkage sites
Dong, Yujie,Shen, Junjie,Li, Weijun,Zhao, Ruiyang,Pan, Yuyu,Song, Qingbao,Zhang, Cheng
, p. 2670 - 2675 (2019)
In this work, we report two isomers composed of 1-phenyl-1H-phenanthro[9,10-d]imidazole (PI), hydroxyl and tetraphenylethylene (TPE), abbreviated as m-PITPE and p-PITPE. It is found that they exhibit similar aggregation-induced emission (AIE) behavior but totally different excited-state intramolecular proton transfer (ESIPT) characteristic, as a result of the different linkage sites of PI on TPE moiety. Theoretical calculations and their different experimental responses to F? demonstrate that only the para-linkage isomer displays ESIPT. In m-PITPE with meta-linkage, the electron cloud distribution only locates at the TPE part in the singlet excited (S1) states, which results in the localized excited state without ESIPT characteristic.
NOVEL TRIBORYLALKENE, PRODUCTION METHOD THEREOF, AND PRODUCTION METHOD OF MULTISUBSTITUTED ALKENE
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Paragraph 0162; 0163; 0180; 0181; 0187; 0188, (2020/03/10)
PROBLEM TO BE SOLVED: To provide a compound as a synthetic intermediate for a tetraarylalkene useful as medicaments and electronic materials. SOLUTION: The invention provides a triborylalkene represented by the general formula (I) in the figure, where Ra represents an optionally substituted aryl group. SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT