219627-07-3Relevant articles and documents
Reaction of AlR3 with [CPh3][B(C6F 5)4]: Facile degradation of [B(C6F 5)4]- by transient [AlR2] +
Bochmann, Manfred,Sarsfield, Mark J.
, p. 5908 - 5912 (1998)
Trimethylaluminum reacts with [CPh3][B(C6F 5)4] at elevated temperatures to give a mixture of AlMe3-x(C6F5)x compounds, depending on the Al/B ratio. AlBui3 reacts significantly faster under β-hydride abstraction. The Al-C6F5 species rapidly react with Cp2ZrMe2 or [Cp2ZrMe] + under C6F5 transfer to give poorly active Cp2ZrMe(C6F5); this reaction may have implications for the deactivation of Cp2ZrMe2/AlR 3/[CPh3][B(C6F5)4] olefin polymerization catalysts.