Cas 219650-49-4,((CH3)5C6H)Ru(C5H3(C6H5)2)(1+)*OSO2CF3(1-)=[((CH3)5C6H)Ru(C5H3(C6H5)2)]OSO2CF3

219650-49-4

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Basic information

Product Name: ((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)⁽¹⁺⁾*OSO₂CF₃^(1-)=[((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)]OSO₂CF₃
Synonyms:
CAS NO:219650-49-4
Molecular Formula:
Molecular Weight: 615.679
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: ((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)⁽¹⁺⁾*OSO₂CF₃^(1-)=[((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)]OSO₂CF₃(CAS DataBase Reference)
NIST Chemistry Reference: ((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)⁽¹⁺⁾*OSO₂CF₃^(1-)=[((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)]OSO₂CF₃(219650-49-4)
EPA Substance Registry System: ((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)⁽¹⁺⁾*OSO₂CF₃^(1-)=[((CH₃)5C₆H)Ru(C₅H₃(C₆H₅)2)]OSO₂CF₃(219650-49-4)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 219650-49-4(Hazardous Substances Data)

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219650-49-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 219650-49-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,1,9,6,5 and 0 respectively; the second part has 2 digits, 4 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 219650-49:
(8*2)+(7*1)+(6*9)+(5*6)+(4*5)+(3*0)+(2*4)+(1*9)=144
144 % 10 = 4
So 219650-49-4 is a valid CAS Registry Number.

219650-49-4Upstream product

219650-49-4Downstream Products

219650-49-4Relevant academic research and scientific papers

Demethylation of coordinated hexamethylbenzene. Carbon-carbon bond activation during ruthenium-mediated [3 + 2] allyl alkyne cycloaddition reactions

Older,Stryker

, p. 5596 - 5598 (1998)

The demethylation of coordinated hexamethylbenzene is integrated into [3 + 2] allyl/alkyne cycloaddition reactions mediated by (η6-hexamethylbenzene)-Ru(η3-allyl)OTf. The reaction proceeds in high yield at or below room temperature and yields methane and (η 3-pentamethylbenzene)ruthenium(1,2-dialkylcyclopentadienyl)+OTf - complexes exclusively. Cycloaddition with carbon-carbon bond activation is general for a range of disubstituted alkynes.

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