219717-33-6Relevant academic research and scientific papers
Reductive Allylic Defluorinative Cross-Coupling Enabled by Ni/Ti Cooperative Catalysis
Lin, Zhiyang,Lan, Yun,Wang, Chuan
supporting information, p. 8316 - 8322 (2019/10/14)
Unactivated alkyl chlorides are abundant building blocks in organic synthesis, but they have been rarely engaged in cross-electrophile coupling. Herein, we report a Ni/Ti-cocatalyzed reductive allylic defluorinative cross-coupling between trifluoromethyl
Synthesis of 1,2-dimethyl-6-(2′-hydroxyisopropyl)-7-methoxynaphthalene, an isomer of emmotin-G methyl ether
Bachute,Desai, Uday V.,Mane
, p. 857 - 860 (2007/10/03)
Ethyl p-methoxystyryl ketone 1 is hydrogenated over Pd-C (5%) to furnish 5-(p-methoxyphenyl)pentan-3-one 2. The alcohol 3, obtained by Grignard reaction of methylmagnesium iodide with the ketone 2, is cyclodehydrated with PPA to give 7-methoxy-1,2-dimethy
