219838-89-8

Basic information

• Product Name: C₅H₄NCMe₂NH(2,6-diisopropylphenyl)
• CAS NO: 219838-89-8
• Molecular Weight: 296.456
• Mol File: 219838-89-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₅H₄NCMe₂NH(2,6-diisopropylphenyl)(CAS DataBase Reference)
• NIST Chemistry Reference: C₅H₄NCMe₂NH(2,6-diisopropylphenyl)(219838-89-8)
• EPA Substance Registry System: C₅H₄NCMe₂NH(2,6-diisopropylphenyl)(219838-89-8)

Safety Data

• Hazardous Substances Data: 219838-89-8(Hazardous Substances Data)

Upstream product

• 75-24-1 trimethylaluminum 
• 900816-53-7 2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]phenylamine 

Downstream Products

• 1031217-61-4 [(κ2-N,N'-C5H4NCMe2N(2,6-diisopropylphenyl))Zr(dimethylamido)3] 
• 1031721-71-7 [(κ2-N,N'-C5H4NCMe2N(2,6-diisopropylphenyl))Zr(benzyl)3] 

Relevant articles and documents

(Amidomethyl)pyridine zirconium and hafnium complexes: Synthesis and structural characterization

A series of 2-formyl and 2-acetylpyridines was condensed with 2,6-diisopropylaniline to yield the corresponding imines. Their reaction with sodium borohydride gave the respective N-arylaminomethylpyridines. Treatment of the N-arylformimino- or -acetiminopyridines with trimethylaluminum followed by hydrolysis furnished a series of the respective substituted N-arylaminoethylpyridine derivatives. Their reaction with tetrabenzylzirconium or tetrakis(dimethylamido)zirconium or -hafnium gave the corresponding (chelate ligand)MX3 systems in a variety of cases. Some of these gave very active ethene polymerization catalysts upon activation with methylalumoxane. Six of the neutral aminoalkylpyridines were characterized by X-ray diffraction, as were eight of the zirconium or hafnium complexes and two aluminum chelate complex systems.