219866-53-2Relevant academic research and scientific papers
Formation of neutral and cationic methyl derivatives of titanium containing cyclopentadienyl and aryloxide ancillary ligation
Fenwick, Andrew E.,Phomphrai, Khamphee,Thorn, Matthew G.,Vilardo, Jonathan S.,Trefun, Christine A.,Hanna, Brigitte,Fanwick, Phillip E.,Rothwell, Ian P.
, p. 2146 - 2156 (2008/10/09)
The formation of dimethyltitanium compounds [CpTi(OAr)Me2] containing cyclopentadienyl and aryloxide ancillary ligation was analyzed. The polymerization of ethylene and γ-olefins was achieved with mixed [Cp(ArO)TiCl2] precursors trea
Formation and reactivity of cationic alkyl derivatives of titanium containing ortho-(1-naphthyl)phenoxide ligation
Thorn, Matthew G.,Vilardo, Jonathan S.,Fanwick, Phillip E.,Rothwell, Ian P.
, p. 2427 - 2428 (2007/10/03)
A series of dimethyl compounds of Ti(IV) have been isolated containing both cyclopentadiene and ortho-arylphenoxide ligation; reaction with [B(C6F5)3] generates corresponding cationic methyl species which eliminate methane and form [Cp(ArO)Ti{CH2B(C6F5)2}(C6F5)] derivatives.
