219874-44-9Relevant academic research and scientific papers
Synthesis and molecular structure of [{Pd2(CH2C6H4P(o-tolyl) 2-κC,F)2(μ3-3,5-dmpz-N,N′,C 4)2Ag(μ-ClO4)}2] (3,5-dmpz = 3,5-dimethylpyrazolato), a silver derivative showing unprecedented η1-azolato coordination
Falvello, Larry R.,Fornies, Juan,Martin, Antonio,Navarro, Rafael,Sicilia, Violeta,Villarroya, Pablo
, p. 2429 - 2430 (1998)
The reaction of [Pd2(CH2C6H4P(o-tolyl) 2-κC,P)2(μ-3,5-dmpz)2] (1) with AgClO4 renders [{Pd2(CH2C6H4P(o-tolyl) 2-κC,P)2(μ3-3,5-dmpz-N,N′,C 4)2Ag(η2-μ-ClO4)} 2] (2), a palladium-silver derivative displaying an unprecedented dmpz bridging ligand η1 bonded to the Ag centers, involving only the C4 atom of each dmpz ligand.
