219926-63-3

Basic information

• Product Name: (+)-(4S)-2,2-Dimethyl-4-[(E)-3-phenylsulfonylprop-1-enyl]-1,3-dioxolane
• Synonyms: (+)-(4S)-2,2-Dimethyl-4-[(E)-3-phenylsulfonylprop-1-enyl]-1,3-dioxolane
• CAS NO: 219926-63-3
• Molecular Weight: 282.361
• Mol File: 219926-63-3.mol

Chemical Properties

• CAS DataBase Reference: (+)-(4S)-2,2-Dimethyl-4-[(E)-3-phenylsulfonylprop-1-enyl]-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(4S)-2,2-Dimethyl-4-[(E)-3-phenylsulfonylprop-1-enyl]-1,3-dioxolane(219926-63-3)
• EPA Substance Registry System: (+)-(4S)-2,2-Dimethyl-4-[(E)-3-phenylsulfonylprop-1-enyl]-1,3-dioxolane(219926-63-3)

Safety Data

• Hazardous Substances Data: 219926-63-3(Hazardous Substances Data)

Upstream product

• 15186-48-8 2,3-isopropylidene-glyceraldehyde 
• 64520-58-7 ethyl (E)-3-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate 
• 873-55-2 sodium benzenesulfonate 
• 198402-59-4 (S,E)-4-(3-bromoprop-1-en-1-yl)-2,2-dimethyl-1,3-dioxolane 

Downstream Products

• 527729-34-6 (+)-(2S)-5-benzenesulfonyl-2-(4-methoxybenzyloxy)-1-tosyloxy-pent-3-ene 
• 527729-31-3 (+)-(2S)-5-benzenesulfonyl-2-methoxymethoxy-1-tosyloxy-pent-3-ene 
• 527729-39-1 (+)-(2S)-5-benzenesulfonyl-1-iodo-2-(4-methoxybenzyloxy)-pent-3-ene 
• 527729-25-5 (+)-(2S)-5-benzenesulfonyl-2-(4-methoxybenzyloxy)-pent-3-en-1-ol 
• 527729-22-2 (+)-(2S)-5-benzenesulfonyl-[1,2]-(4-methoxybenzyliden)-pent-3-ene-1,2-diol 
• 527729-60-8 (+)-(1R,2R)-2-(2-benzenesulfonylvinyl)-1-(4-methoxybenzyloxy)-cyclopropane 
• 527729-48-2 (-)-(1R,2S)-2-(2-benzenesulfonylvinyl)-1-(4-methoxybenzyloxy)-cyclopropane 
• 527729-78-8 (-)-(1R,2R)-2-(2-benzenesulfonylethyl)-1-(4-methoxybenzyloxy)-cyclopropane 
• 527729-71-1 (-)-(1R,2S)-2-(2-benzenesulfonylethyl)-1-(4-methoxybenzyloxy)-cyclopropane 
• 527729-19-7 (-)-(2S)-5-benzenesulfonyl-1-iodo-2-tert-butyldimethylsilyloxy-pent-3-ene 
• 527729-80-2 (-)-(1R,2R)-2-(2-benzenesulfonylethyl)-1-tert-butyldimethylsililoxy-cyclopropane 
• 527729-73-3 (-)-(1R,2S)-2-(2-benzenesulfonylethyl)-1-tert-butyldimethylsililoxy-cyclopropane 
• 527729-63-1 (-)-(1R,2R)-2-(2-benzenesulfonylvinyl)-1-tert-butyldimethylsililoxy-cyclopropane 
• 527729-51-7 (-)-(1R,2S)-2-(2-benzenesulfonylvinyl)-1-tert-butyldimethylsililoxy-cyclopropane 

Relevant articles and documents

One-pot synthesis of aryl sulfones from alcohols

A one-pot synthesis of aryl sulfones from primary alcohols is described. Alcohols were treated with N-bromosuccinimide and triphenylphosphine, followed by addition of sodium arenesulfinate with a catalytic amount of tetrabutylammonium iodide to afford the aryl sulfones in good to high yields.

Stereoselective synthesis of 1-hydroxymethyl-4-phenylsulfonylbutadienes

Stereoselective syntheses of 1-hydroxymethyl-4-phenylsulfonylbutadienes were achieved from unsaturated sulfones which were easily obtained from D-Mannitol.